Vanadium(III) complexes incorporating the silylamino(disilylamido) ligand [(Me3Si)N{CH2CH2N(SiMe3)} 2]2- [N{N¿}2]2-. Synthesis and crystal structure of the dimeric, non-metallocene vanadium(III) hydride [{V(N{N¿}2)}2(µ-H)2]

Clancy, Gerald P, Clark, Howard C S, Cloke, F Geoffrey, Clentsmith, Guy K B and Hitchcock, Peter B (1999) Vanadium(III) complexes incorporating the silylamino(disilylamido) ligand [(Me3Si)N{CH2CH2N(SiMe3)} 2]2- [N{N¿}2]2-. Synthesis and crystal structure of the dimeric, non-metallocene vanadium(III) hydride [{V(N{N¿}2)}2(µ-H)2]. Journal of the Chemical Society - Dalton Transactions, 19. pp. 3345-3347. ISSN 03009246

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Abstract

Three vanadium(III) complexes incorporating the chelating silylamino(disilylamido) ligand [(Me3Si)N{CH2CH2N-(SiMe3)} 2]2- ([N{N¿}2]2-) have been reported. Addition of Li2[N{N¿}2] to VCl3THF cleanly yielded the vanadium(III) chloride [{V(N{N¿}2)Cl}2] 1, from which the vanadium(III) hydrocarbyl [V(N{N¿}2){CH(SiMe3)2}] 2 could be generated by means of salt metathesis. Hydrogenolysis of 2 under dihydrogen produced the thermally stable, dimeric vanadium(III) hydride [{V(N{N¿}2)}2(µ-H)2] 3. The solid state structure of 3 was determined. © The Royal Society of Chemistry 1999.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 18:09
Last Modified: 19 Mar 2013 13:52
URI: http://sro.sussex.ac.uk/id/eprint/15007
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